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Turning Trash into Treasure: Silicon Carbide Nanoparticles from Coal Gangue and High-Carbon Waste Materials

Affiliation
Shaanxi Key Laboratory of Chemical Reaction Engineering, Collaborative Innovation Center for Clean and Efficient Utilization of Low-Rank Coal of Northern Shaanxi, Research Institute of Comprehensive Energy Industrial Technology, School of Chemistry & Chemical Engineering, Yan’an University, Yan’an 716000, China;(K.G.);(Y.Z.);(B.W.);(S.L.);(Q.W.);(Y.Z.);(F.F.)
Gao, Kaixing;
Affiliation
Shaanxi Key Laboratory of Chemical Reaction Engineering, Collaborative Innovation Center for Clean and Efficient Utilization of Low-Rank Coal of Northern Shaanxi, Research Institute of Comprehensive Energy Industrial Technology, School of Chemistry & Chemical Engineering, Yan’an University, Yan’an 716000, China;(K.G.);(Y.Z.);(B.W.);(S.L.);(Q.W.);(Y.Z.);(F.F.)
Zhang, Yao;
Affiliation
Shaanxi Key Laboratory of Chemical Reaction Engineering, Collaborative Innovation Center for Clean and Efficient Utilization of Low-Rank Coal of Northern Shaanxi, Research Institute of Comprehensive Energy Industrial Technology, School of Chemistry & Chemical Engineering, Yan’an University, Yan’an 716000, China;(K.G.);(Y.Z.);(B.W.);(S.L.);(Q.W.);(Y.Z.);(F.F.)
Wang, Binghan;
Affiliation
Shaanxi Key Laboratory of Chemical Reaction Engineering, Collaborative Innovation Center for Clean and Efficient Utilization of Low-Rank Coal of Northern Shaanxi, Research Institute of Comprehensive Energy Industrial Technology, School of Chemistry & Chemical Engineering, Yan’an University, Yan’an 716000, China;(K.G.);(Y.Z.);(B.W.);(S.L.);(Q.W.);(Y.Z.);(F.F.)
Zhang, Zhuangzhuang;
Affiliation
Shaanxi Key Laboratory of Chemical Reaction Engineering, Collaborative Innovation Center for Clean and Efficient Utilization of Low-Rank Coal of Northern Shaanxi, Research Institute of Comprehensive Energy Industrial Technology, School of Chemistry & Chemical Engineering, Yan’an University, Yan’an 716000, China;(K.G.);(Y.Z.);(B.W.);(S.L.);(Q.W.);(Y.Z.);(F.F.)
Luo, Sen;
Affiliation
Shaanxi Key Laboratory of Chemical Reaction Engineering, Collaborative Innovation Center for Clean and Efficient Utilization of Low-Rank Coal of Northern Shaanxi, Research Institute of Comprehensive Energy Industrial Technology, School of Chemistry & Chemical Engineering, Yan’an University, Yan’an 716000, China;(K.G.);(Y.Z.);(B.W.);(S.L.);(Q.W.);(Y.Z.);(F.F.)
Wang, Qian;
Affiliation
Shaanxi Key Laboratory of Chemical Reaction Engineering, Collaborative Innovation Center for Clean and Efficient Utilization of Low-Rank Coal of Northern Shaanxi, Research Institute of Comprehensive Energy Industrial Technology, School of Chemistry & Chemical Engineering, Yan’an University, Yan’an 716000, China;(K.G.);(Y.Z.);(B.W.);(S.L.);(Q.W.);(Y.Z.);(F.F.)
Zhen, Yanzhong;
Affiliation
Shaanxi Key Laboratory of Chemical Reaction Engineering, Collaborative Innovation Center for Clean and Efficient Utilization of Low-Rank Coal of Northern Shaanxi, Research Institute of Comprehensive Energy Industrial Technology, School of Chemistry & Chemical Engineering, Yan’an University, Yan’an 716000, China;(K.G.);(Y.Z.);(B.W.);(S.L.);(Q.W.);(Y.Z.);(F.F.)
Fu, Feng;
Affiliation
Institut für Anorganische Chemie, Eberhard Karls Universität Tübingen, Auf der Morgenstelle 18, D-72076 Tübingen, Germany;
Liang, Yucang

To reduce solid waste production and enable the synergistic conversion of solid waste into high-value-added products, we introduce a novel, sustainable, and ecofriendly method. We fabricate nanofiber and nanosheet silicon carbides (SiC) through a carbothermal reduction process. Here, the calcined coal gangue, converted from coal gangue, serves as the silicon source. The carbon sources are the carbonized waste tire residue from waste tires and the pre-treated kerosene co-refining residue. The difference in carbon source results in the alteration of the morphology of the SiC obtained. By optimizing the reaction temperature, time, and mass ratio, the purity of the as-made SiC products with nanofiber-like and nanosheet-like shapes can reach 98%. Based on the influence of synthetic conditions and the results calculated from the change in the Gibbs free energy of the reactions, two mechanisms for SiC formation are proposed, namely the reaction of intermediate SiO with CO to form SiC-nuclei-driven nanofibrous SiC and the SiO-deposited carbon surface to fabricate nuclei-induced polymorphic SiC (dominant nanosheets). This work provides a constructive strategy for preparing nanostructured SiC, thereby achieving “turning trash into treasure” and broadening the sustainable utilization and development of solid wastes.

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Editor:
Baláž, Matej
Published in:
Molecules  
Vol. 30, No. 7 (31.03.2025)
Volume:
30
No.:
7
Date Issued:
31.03.2025
DOI:
10.3390/molecules30071562
Language:
English
Type of Resource:
Text
Keywords:
re-utilization of waste resources; turning trash into treasure; nanostructured silicon carbide; morphological control; carbothermal reduction reaction
DDC:
610 Medizin und Gesundheit

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